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Lithium Ion Chargeable Batteries Modified by Kazunori Ozawa

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Lithium Ion Normal rechargeable Batteries

Modified by Kazunori Ozawa

The Editor Doctor Kazunori Ozawa Enax, Inc. President & CEO 2-11-19 Otowa, Bunkyo-ku Tokyo 112-0013 Japan

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All rights reserved (including those of translation into different languages). Simply no part of this book may be produced in any kind – by simply photo producing, microfilm, or any type of other means – neither transmitted or translated into a machine dialect without created permission in the publishers. Registered names, trademarks, etc . used in this book, even though not specifically marked as such, are not to be considered unprotected by law. Printed in the Federal Republic of Indonesia Printed on acid-free conventional paper Typesetting Laserwords Private Limited, Chennai, India Printing Strauss GmbH, M¨ rlenbach um Binding Litges & Dopf GmbH, Heppenheim Cover Style Adam-Design, Weinheim ISBN: 978-3-527-31983-1



Preface XI XIII

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General Concepts one particular Kenzo Matsuki and Kazunori Ozawa Brief Outline of Batteries 1 Galvanic Cell System – Aqueous Electrolyte System 2 Lithium-Cell System – Nonaqueous Electrolyte System 4 Early Development of Li ion Batteries 5 Ceramics Development Capability a few Coating Technology 6 LiPF6 as a Salt for Electrolytes 6 Graphite Conductor in the Cathode 6 Using Hard Carbon pertaining to the Valve 6 Nonwoven Shut-down Separator 6 Ni-Plated Fe Can 7 Toward a Realistic Objective 7 Referrals 9 Lithium Insertion Elements Having Spinel-Framework Structure intended for Advanced Power packs 11 Kingo Ariyoshi, Yoshinari Makimura, and Tsutomu Ohzuku Introduction 14 Structural Description of Spinel 12 Derivatives of Spinel-Framework Structure 15 Superlattice Set ups Derived from ‘‘Spinel'' 15 Types of Superstructure Produced from ‘‘Spinel'' twenty Electrochemistry of Lithium Insertion Materials Having Spinel-Framework Composition 24 Li (symbol) Manganese Oxides (LMO) twenty-four Lithium Ti Oxide (LTO) 27


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Lithium Ion Rechargeable Batteries. Modified by Kazunori Ozawa Copyright laws п›™ 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim ISBN: 978-3-527-31983-1



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Lithium Pennie Manganese Oxide (LiNiMO) twenty-eight An Application of Lithium Insertion Materials Having Spinel-Framework Framework to doze V ‘‘Lead-Free'' Accumulators twenty nine Twelve-Volt Batteries Consisting of Lithium Titanium Oxide (LTO) and Lithium Manganese Oxide (LMO) 32 Twelve-Volt Batteries Including Lithium...

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